Publications

2023

233. F. Medici, S. Resta, S. Andolina, M. Benaglia "Recent Advances in Enantioselective Catalytic Electrochemical Organic Transformations" Catalysts,2023, 13, 944
232. C. Rizzo, S. Marullo, M. Benaglia, F. D'Anna "DBS-based Eutectogels: organized “vessels” to perform the Michael Addition Reaction" Eur. J. Org. Chem. ,2023, 26, e202300263
231. C. Faverio, M. F. Boselli, T. Ruggiero, L. Raimondi, M. Benaglia "Hydrogen bond-mediated organocatalytic enantioselective reduction of nitroalkenes in deep eutectic solvents" Tetrahedron Chem,2023, 6, 100038
230. P. Camarero Gonzalez, S. Rossi, M. Sanz, F. Vasile, M. Benaglia "Synthesis of Tetrasubstituted Nitroalkenes and Preliminary Studies of Their Enantioselective Organocatalytic Reduction" Molecules,2023, 28, 3156
229. M. Krstić, M. Benaglia, M. Gazzotti, E. Colombo, M. Sanz "Enantioselective Organocatalytic Addition of Nitromethane to Trifluoromethylaryl Ketoimines Promoted by Electron-Rich Bifunctional Iminophosphoranes" Adv. Synth. Catal,2023, 365, 1093-1098
228. F. Medici, A. Puglisi, S. Rossi, L. Raimondi, M. Benaglia "Stereoselective [2+2] Photodimerization: a Viable Strategy for the Synthesis of Enantiopure Cyclobutane Derivatives." Org. Biomol. Chem.,2023, 21, 2899-2904
227. F. Medici, F. Montinari, E. Donato, L. Raimondi, M. Benaglia "A convenient protocol for a zinc-catalysed synthesis of electron-poor indoles" Tetrahedron Lett.,2023, 116, 154340
226. M. F. Boselli, N. Intini, A. Puglisi, L. Raimondi, S. Rossi, M. Benaglia "Enantioselective catalytic addition of N-acyl radicals: in batch and in flow organophotoredox α-amination of aldehydes" Eur. J. Org. Chem. ,2023, 26, e2022013

2022

225. F. Herbrik, S. Rossi, M. Sanz, A. Puglisi, M. Benaglia "Immobilized Eosin Y for the photocatalytic oxidation of tetrahydroisoquinolines in flow" ChemCatChem ,2022, e202200461.
224. F. Franco, S. Meninno, J. Overgaard, S. Rossi, M. Benaglia, A. Lattanzi "Catalytic Entry to Enantioenriched Triflones Featuring a Quaternary Stereocenter" Org. Lett. ,2022, 24 4371–4376..
223. R. Westphal, E. Venturini Filho, F. Medici, M. Benaglia, S. J. Greco "Stereoselective domino reactions in the synthesis of spiro compounds" Synthesis ,2022, 54 2927–2975.
222. F. Herbrik , M. Sanz, A. Puglisi, S. Rossi, M. Benaglia "Enantioselective organophotocatalytic telescoped synthesis of a chiral privileged active pharmaceutical ingredient" Chem. Eur. J. ,2022, 28 (33) e202200164.
221. B. C. Lemos, E. Venturini Filho, R. G. Fiorot, F. Medici, S. J. Greco, M. Benaglia "Enantioselective Povarov reactions: An update of a powerful catalytic synthetic methodology" Eur. J. Org. Chem , 2022, e202101171 (1 of 22).

2021

220. F. Medici, S. Resta, A. Puglisi, S. Rossi, L. Raimondi. M. Benaglia "Electrochemical Organic Synthesis of Electron-Rich Biaryl Scaffolds: An Update" Molecules ,2021, 26 6968.
219. A. Puglisi, S. Rossi, F. Herbrik, F. Medici, M. Benaglia "In flow enantioselective homogeneous organic synthesis" Green Processing and Synthesis ,2021, 10 1-11.
218. S. Rossi, A. Puglisi, L. Raimondi, M. Benaglia, "Recent advances in the use of 3D-printed devices in organic synthesis including enantioselective catalysis" Chapter in the book "Recent Advances and Perspectives in Enantioselective Catalysis" (Ed. A. Marinetti), World Scientific publisher
217. C. Faverio, M. Boselli, P. Camarero Gonzalez, A. Puglisi, M. Benaglia, "Nitroalkene reduction in deep eutectic solvents promoted by BH3-NH3" Beilstein J. Org. Chem. ,2021, 17 1041-1047.
216. F. Franco, S. Meninno, A. Lattanzi, A. Puglisi, M. Benaglia, "Continuous Flow Synthesis of α Trifluoromethylthiolated Esters and Amides from Carboxylic Acids: a Telescoped Approach" J. Org. Chem., 2021, doi:10.1021/acs.joc.1c01270
215. F. Medici, S. Resta, P. Presenti, L. Caruso, A. Puglisi, L. Raimondi, S. Rossi, M. Benaglia, "Stereoselective Visible-Light Catalyzed Cyclization of Bis(enones): A Viable Approach to the Synthesis of Enantiomerically Enriched Cyclopentane Rings" Eur. J. Org. Chem. ,2021, 4521-4524.
214. M. Pirola, C. Faverio, M. Orlandi, M. Benaglia, "Metal-Free Deoxygenation of Chiral Nitroalkanes: An Easy Entry to α-Substituted Enantiomerically Enriched Nitriles" Chem. Eur. J. ,2021, 27, 10247-10250.
213. M. F. Boselli, C. Faverio, E. Massolo, L. Raimondi, A. Puglisi, M. Benaglia, "Stereoselective Synthesis of Chiral α-SCF3-β-Ketoesters Featuring a Quaternary Stereocenter" Symmetry ,2021, 13, 92.
212. S. Meninno, F. Franco, M. Benaglia, A. Lattanzi, "Pyrazoleamides in Catalytic Asymmetric Reactions: Recent Advances" Adv. Synth. Catal. ,2021, 363, 3380−3410.
211. E. Massolo and M. Benaglia, "Stereoselective organocascades: from fundamentals to recent developments" Chapter in Organocatalysis: Stereoselective Reactions and Applications in Organic Synthesis (DeGruyter, M. Benaglia editor) Physical Sciences Reviews, 2021, doi:10.1515/psr-2018-0096

2020

210. S. Rossi, M. Benaglia, L. Raimondi, "DFT investigation on Lewis base-catalyzed Lewis acid-mediated reactions: Hypervalent silicon species as chiral organocatalysts in (direct) aldol reaction" New J. Chem. ,2020, 44, 19288-19293.
209. C. Faverio, M. F. Boselli, L. Raimondi, M. Benaglia. "Ammonia-borane mediated reduction of nitroalkenes" SynOpen,2020, 4 116-122.
208. S. Rossi, A. Puglisi, L. Raimondi, M. Benaglia "3D printed catalytically active devices in organic synthesis" Chimica Oggi - Chemistry Today ,2020, 38, 36-39.
207. C. Faverio, M. F. Boselli, F. Medici, M. Benaglia, "Ammonia borane as a reducing agent in organic synthesis" Org. Biomol. Chem ,2020, 18, 7789
206. F. Herbrik, P. Camarero González , M. Krstic , A. Puglisi , M. Benaglia , M. A. Sanz , S. Rossi "Eosin Y: homogeneous photocatalytic in-flow reactions and solid supported-catalysts for in-batch synthetic transformation" Appl. Sci. 2020 ,2020, 10, 5596, doi:10.3390/app10165596
205. E. Massolo, M. Pirola, M. Benaglia, "Amide bond formation strategies: latest advances on a dateless transformation" Eur. J. Org. Chem. ,2020, 4641-4651.
204. F. Franco, S. Mennino, A. Lattanzi, M. Benaglia, "Formal α-trifluoromethylthiolation of carboxylic acid derivatives via N-acyl pyrazoles" Chem Comm,2020, 3073-3076.
203. E. Massolo, M. Pirola, A. Puglisi, L. S. Rossi, M. Benaglia, "A one pot protocol to convert nitro-arenes into N-aryl amides" RSC Advances, 2020, 10, 4040-4044.
202. S. Rossi, A. Puglisi, L. Raimondi, M. Benaglia "Stereolitography 3D-printed catalytically active devices in organic synthesis" Catalysts, 2020, 10, 109-117.

2019

201. S. Rossi, T. Benincori, L. Raimondi, M. Benaglia "3,3’-Bithiophene-based Chiral Bisphosphine Oxides as organocatalysts in silicon-derived Lewis acids mediated reactions" Synlett, 2019, accepted for publication
200. L. Caruso, A. Puglisi, E. Gillon, M. Benaglia "Organocatalytic Michael addition to (D)-mannitol-derived enantiopure nitroalkenes: a valuable strategy for the synthesis of densely functionalized chiral molecules." Molecules, 2019, 24, 4588-4597
199. M. Pirola, A. Puglisi, L. Raimondi, A. Forni, M. Benaglia "Evaluation of in-batch and in-flow synthetic strategies towards the stereoselective synthesis of a fluorinated analogue of retro-thiorphan" Molecules, 2019, 24 2260-2269
198. I. Vigentini, V. Fabrizio, F. Dellaca, S. Rossi, I. Azario, C. Mondin, M. Benaglia, R. Foschino "Set-Up of Bacterial Cellulose Production From the Genus Komagataeibacter and Its Use in a Gluten-Free Bakery Product as a Case Study Frontiers In Microbiology, 2019, 10 1953-1963
197. V. M. Abbinante, M. Benaglia, S. Rossi; T. Benincori, R. Cirili, M. Pierini, "TetraPh-Tol-BITIOPO: a new atropisomeric 3,3′-bithiophene based phosphine oxide as an organocatalyst in Lewis base-catalyzed Lewis acid mediated reactions Org Biomol Chem, 2019, 17, 7474-7481

2018

196. S. Rossi, A. Puglisi, L. Raimondi, M. Benaglia, " Synthesis of alpha-trifluoromethylthio carbonyl compounds: a survey of the methods for the direct introduction of the SCF3 group on to organic molecules, ChemCatChem, 2018, 10, 2717-2733.
195. M. Pirola, M. Benaglia, M. E. Compostella, L. Raimondi, A. Puglisi, "A continuous flow, two-steps, metal-free process for the synthesis of differently substituted chiral 1,2-diamino derivatives" Synthesis, 2018, 50, 1430-1438.
194. S. Rossi, A. Puglisi, M. Benaglia, "Additive Manufacturing Technologies: 3D printing in Organic Synthesis", ChemCatChem 2018, 10, 1512-1525.
193. S. S. Abubakar, M. Benaglia, S. Rossi, R. Annunziata "Organocatalytic α-trifluoromethylthiolation of silylenol ethers: batch vs continuous flow reactions" Catal. Today , 2018, 30894-101.

2017

192. S. Rossi, M. Ziliani, R. Annunziata, M. Benaglia "Novel chiral bis-phosphoramides as organocatalysts for tetrachlorosilane-mediated reactions" Molecules, 2017, 22, 2181-2192
191. E. Massolo, L. Raimondi, M. Benaglia "In flow/batch synthesis of chiral amines" Chem Today - Chimica Oggi, 2017, 35, 34-36.
190. D. Brenna, S. Rossi, F. Cozzi, M. Benaglia "Iron catalyzed diastereoselective hydrogenation of chiral imines" Org. Biomol. Chem, 2017, 15,5685-5688.
189. R. Porta, M. Benaglia, R. Annunziata, A. Puglisi, G. Celentano "Solid supported chiral N-picolylimidazolidinones: recyclable catalysts for the enantioselective,metal- and H2-free reduction of imines in batch and in flow mode", Adv. Synth. Catal., 2017, 359, 2375-2382.
188. S. Rossi, D. Brenna, R. Porta, A. Puglisi, M. Benaglia "Stereoselective catalytic APIs synthesis in home-made 3D-printed mesoreactors", Angew. Chem. Int. Ed. 2017, 2017, 56, 4290-4294.
187. D. Brenna, M. Pirola, L. Raimondi, A. J. Burke, M. Benaglia "A stereoselective, catalytic strategy for the in-flow synthesis of advanced precursors of Rasagiline and Tamsulosin." Bioorg. Med. Chem., 2017, DOI: 10.1016/j.bmc.2017.01.023
186. D. Brenna, R. Porta, E. Massolo, L. Raimondi, M. Benaglia "A new class of low-loading catalysts for a highly enantioselective, metal-free imine reduction of wide general applicability." ChemCatChem, 2017, 9, 941-945.
185. D. Brenna, M. Benaglia, R. Porta, S. D. Fernandes, A. J. Burke "Stereoselective metal-free reduction of chiral imines in batch and in flow mode. A convenient strategy for the synthesis of chiral Active Pharmaceutical Ingredients." Eur. J. Org. Chem, 2017, 1, 39-44.

2016

184. R. Porta, A. Puglisi, G. Colombo, S. Rossi, M. Benaglia "Continuous-flow synthesis of primary amines: Metal-free reduction of aliphatic and aromatic nitro derivatives with trichlorosilane" Beilstein J. Org. Chem., 2016, 12, 2614-2619.
183. D. Brenna, E. Massolo, A. Puglisi, S. Rossi, G. Celentano, M. Benaglia, V. Capriati "Towards the development of continuous, organocatalytic, and stereoselective reactions in deep eutectic solvents" Beilstein J. Org. Chem., 2016, 12, 2620-2626.
182. S. D. Fernandes, R. Porta, P. C. Barrulas, A. Puglisi, A. J. Burke, M. Benaglia "Stereoselective Reduction of Imines with Trichlorosilane using Solid-Supported Chiral Picolinamides" Molecules, 2016, 21, 1182-1190.
181. E. Massolo, D. Brenna, N. Gaggero, F. Cozzi, L. Raimondi, M. Benaglia "2-Carboxythioester-1,3-dithiane: a Functionalized Masked Carbonyl Nucleophile for the Organocatalytic Enantioselective Michael Addition to Enones" Synlett, 2016, 27, 2716-2720.
180. M. Orlandi, D. Brenna, R. Harms, S. Jost, M. Benaglia "Recent developments in the reduction of aromatic and aliphatic nitro compounds to amines. " Org. Process Res. Dev., 2016, 20, DOI: 10.1021/acs.oprd.6b00205
179. M. Orlandi, M. Benaglia, M. Ceotto "Kinetics versus thermodynamics in the proline catalyzed aldol reaction" Chem. Sci., 2016, 7, 5421-5427.
178. S. Rossi, A. Puglisi, M. Benaglia, D. M. Carminati, D. Intrieri, E. Gallo "Synthesis in mesoreactors: Ru(porphyrin)CO-catalyzed aziridination of olefins under continuous flow conditions" Catal. Sci. Technol., 2016, 6, 4700-4704.
177. M. Orlandi, M. Benaglia, F. Tosi, R. Annunziata, F. Cozzi "HSiCl3-mediated Reduction of Nitro-derivatives to Amines: Is Tertiary amine-stabilized SiCl2 the Actual Reducing Species?" J. Org. Chem., 2016, 81, 3037-3041.
176. R. Porta, M. Benaglia, A. Puglisi "Flow chemistry: recent developments in the synthesis of pharmaceutical products" Org. Process Res. Dev. 2016, 20, 2-25.
175. E. Massolo, M. Benaglia, S. Palmieri, V. Capriati, F. M. Perna "Stereoselective organocatalysed reactions in deep eutectic solvents: highly tunable and biorenewable reaction media for sustainable organic synthesis" Green Chem., 2016, 18, 792-797.

2015

174. A. Genoni, M. Benaglia, E. Mattiolo, Sergio Rossi, L. Raimondi, P. C. Barrulas, A. J. Burke "Synthesis of an Advanced Precursor of Rivastigmine: Cinchona-derived Quaternary Ammonium Salts as Organocatalysts for Stereoselective Imine Reductions" Tetrahedron. Lett., 2015, 56, 5752-5756.
173. M. Orlandi, F. Tosi, M. Bonsignore, M. Benaglia "Metal-Free Reduction of Aromatic and Aliphatic Nitro-compounds to Amines: a HSiCl3-mediated Reaction of Wide General Applicability" Org. Lett., 2015, 17, 3941-3943.
172. R. Porta, M. Benaglia, F. Coccia, S. Rossi, A. Puglisi "Enantioselective Organocatalysis in Microreactors: Continuous flow Synthesis of a (S)-Pregabalin Precursor and (S)-Warfarin" Symmetry, 2015, 7, 1395-1409.
171. S. Rossi, M. Benaglia, D. Brenna, R. Porta, M. Orlandi "Three Dimensional (3D) Printing: A Straightforward, User-Friendly Protocol To Convert Virtual Chemical Models to Real-Life Objects" J. Chem. Educ., 2015, 13, 1398-1401.
170. A. Puglisi, M. Benaglia, R. Porta, F. Coccia "Organocatalysis in flow (review)." Current Organocatalysis, 2015, accepted.
169. E. Massolo, M. Benaglia, A. Genoni, R. Annunziata, G. Celentano, N. Gaggero "Stereoselective reaction of 2-carboxythioesters-1,3-dithiane with nitroalkenes: an organocatalytic strategy for the asymmetric addition of a glyoxylate anion equivalent" Org. Biomol. Chem, 2015, 13, 5591-5596.
168. S. Rossi, M. Benaglia, R. Cirilli, T. Benincori "Synthesis of novel chiral bisthiophene-based phosphine oxides as Lewis bases in organocatalytic stereoselective reactions " Asymm. Catalysis, 2015, 217-25.
167. S. Rossi, M. Benaglia, R. Porta, L, Cotarca, P. Maragni, M. Verzini "A stereoselective catalytic nitroaldol reaction as key step in a novel strategy for the synthesis of the renin inhibitor Aliskiren" Eur. J. Org. Chem., 2015, 2531-2537.
166. E. Massolo, M. Benaglia, M. Orlandi, S. Rossi, G. Celentano "Enantioselective organocatalytic reduction of b-trifluoromethyl nitroalkenes: an efficient strategy for the synthesis of chiral b-trifluoromethyl amines." Chemistry, Eur. J., 2015, 21, 3589-3595
165. R. Porta, M. Benaglia, F. Coccia, F. Cozzi, A. Puglisi "Solid supported 9-amino-9-deoxy-epi-quinine as efficient organocatalysts for stereoselective reactions in batch and under continuous flow conditions" Adv. Synth. Catal, 2015, 357, 377-383.

2014

164. E. Massolo, M. Benaglia, D. Parravicini, D. Brenna, R. Annunziata "Synthesis of highly decorated chiral 2-nitro-cyclohexane carboxylic esters through microwave-assisted organocatalyzed cascade reactions" Tetrahedron Letters, 2014, 55, 6639-6642.
163. P. Barrulas, A. Genoni, M. Benaglia, A. Burke "Cinchona-Derived Picolinamides: Effective Organocatalysts for Stereoselective Imine Hydrosilylation" Eur. J. Org. Chem, 2014, 33, 7339-7442.
162. S. Rossi, M. Benaglia, A. Puglisi, C.C. De Filippo, M. Maggini "Continuous-flow stereoselective synthesis in microreactors: nucleophilic additions to nitrostyrenes organocatalyzed by a chiral bifunctional catalyst" J. Flow Chem, 2014, 5, 17-21.
161. R. Porta, M. Benaglia, A. Puglisi, A. Mandoli, A. Gualandi, P.G. Cozzi "A catalytic reactor for organocatalyzed enantioselective continuous flow alkylation of aldehydes" ChemSusChem , 2014, 7, 3534-3540.
160. L. Raimondi, M. Benaglia, F. Cozzi "Aliphatic C-H/π and Heteroatom/π Interactions in some N-Aryl-3,4-(9',10'-Dihydroanthracene-9',10'-diyl)-Succinimides." Eur. J. Org. Chem, 2014, 23, 4993-4998.
159. P. Barrulas, M. Benaglia, A. Burke "Synthesis of novel organocatalysts derived from Cinchona Alkaloids for asymmetric aldol reactions" Tetrahedron, Asymmetry, 2014, 25, 923-935.
158. S. Rossi, M. Benaglia, E. Massolo, L. Raimondi "Organocatalytic strategies for enantioselective metal-free reduction" Catal. Science Technol., 2014, 9, 2708-2723.
157. R. Porta M. Benaglia, V. Chiroli, F. Coccia, A. Puglisi "Stereoselective Diels-Alder reactions promoted under continuous-flow conditions by silica supported chiral organocatalysts" Isr. J. Chem., 2014, 54, 381-394.
156. S. Cauteruccio, D. Dova, M. Benaglia, A. Genoni, M. Orlandi, E. Licandro "Synthesis, Characterization and Organocatalytic Activity of Chiral Tetrathiahelicene Diphosphine Oxides" Eur. J. Org. Chem., 2014, 2694-2702.
155. V. Chiroli, M. Benaglia, A. Puglisi, R. Porta, R. P. Jumde, A. Mandoli "A chiral organocatalytic polymer-based monolithic reactor" Green Chem, 2014, 16, 2798-2806.
154. S. Rossi, M. Benaglia, A. Genoni "Organic reactions mediated by tetrachlorosilane" Tetrahedron, 2014, 70, 2065-2080.
153. E. Massolo, M. Benaglia, A. Palmieri, G. Celentano "Stereoselective addition of 1,3-diketones to β-nitroacrylates catalyzed by chiral metal-free bifunctional catalysts" Asian J. Org. Chem., 2014, 3, 416-420
152. E. Massolo, M. Benaglia, R. Annunziata, A. Palmieri, G. Celentano, A. Forni "Stereoselective synthesis of highly functionalized chiral 2-nitro-cyclohexane carboxylic esters via catalytic dienamine addition to β-substituted-β-nitroacrylates." Adv. Synth. Catal., 2014, 356, 493-500.

2013

151. A. Puglisi, M. Benaglia, R. Annunziata, V. Chiroli, R. Porta, A. Gervasini "Chiral hybrid inorganic-organic materials: synthesis, characterization and application in stereoselective organocatalytic cycloadditions" J. Org. Chem., 2013, 78, 11326-11334.
150. S. Orlandi, M. Benaglia, M. Ghisetti, G. Pozzi "Synthesis and catalytic activity of fluorous chiral primary amine-thioureas" New Journal of Chemistry, 2013, 37, 4140-4147.
149. S. Mondini, A. Puglisi, M. Benaglia, D. Ramella, C. Drago, A. M. Ferretti, A. Ponti "Magnetic Nanoparticles Conjugated To Chiral Imidazolidinone As Recoverable Catalyst" Journal of Nanoparticles Research, 2013, 15, 2025-2036.
148. A. Genoni, M. Benaglia, E. Massolo, S. Rossi, "Stereoselective metal-free catalytic synthesis of chiral trifluoromethyl aryl and alkyl amines" Chem. Commun., 2013, 49, 8365-8367.
147. V. Chiroli, M. Benaglia, F. Cozzi, A. Puglisi. R. Annunziata, G. Celentano, "Continuous-flow stereoselective organocatalyzed Diels Alder reactions in a chiral catalytic -homemade- HPLC column" Organic Letters , 2013, 15, 3590-3593.
146. C. Biaggi, M. Benaglia, M. Ortenzi, E. Micotti, C. Perego, M.-G. De Simoni, "Easily Available, Low Cost 19F-MRI Agents: Poly(ethylene-glycol)-functionalized Fluorinated Ethers" J. Fluorine Chem., 2013, 153, 172-177.
145. A. Genoni, M. Benaglia, S. Rossi, G. Celentano, "Enantiomerically Pure Bithiophene Diphosphine Oxides as Catalysts for Direct Double Aldol Reactions" Chirality, 2013, 25, 643-647.
144. A. Puglisi, M. Benaglia, V. Chiroli, "Stereoselective organic reactions promoted by immobilized chiral catalysts in continuous flow systems " Green Chem ., 2013, 15, 1790-1813.
143. M. Orlandi, M. Benaglia, L. Raimondi, G. Celentano, "2-Aminoimidazolyl and 2-Aminopyridyl (S)-Prolinamides as Versatile Multifunctional Organic Catalysts for Aldol, Michael, and Diels-Alder reactions" Eur. J. Org. Chem., 2013, 12, 2346-2354.
142. M. Bonsignore, M. Benaglia, L. Raimondi, M. Orlandi, G. Celentano, "Enantioselective reduction of ketoimines promoted by easily available (S)-proline derivatives" Beilstein J. Org. Chem. 2013, 9, 633-640.
141. G. Cappelletti, S. Ardizzone, D. Meroni, G. Soliveri, M. Ceotto, C. Biaggi, M. Benaglia, L. Raimondi. "Wettability of bare and fluorinated silanes: A combined approach based on surface free energy evaluations and dipole moment calculations" Journal of colloid and interface science, 2013, 389, 284-291.

2012

140. M. Benaglia, M. Bonsignore, "METODO PER LA RIDUZIONE DI NITRO DERIVATI AD AMMINE", Patent n: MI2012A001489, 06/09/2012
139. M. Benaglia, A. Genoni, M. Bonsignore, "Enantioselective organocatalytic reductions Stereoselective Organocatalysis : From C-C to C-heteroatom bond formation" 2012 ed. Ramon Rios Torres, Wiley.
138. A. Puglisi, M. Benaglia, E. Massolo, G. Celentano Poly(methylhydrosiloxane)-supported chiral thiourea-based bifunctional catalysts. Recyclable Catalysis, 2012, 1, 1-5.
137. M. Bonsignore, M. Benaglia, F. Cozzi, A. Genoni, S. Rossi, L. Raimondi Readily available (S)-proline-derived organocatalysts for the Lewis acid-mediated Lewis base-catalyzed stereoselective aldol reactions of activated thioesters Tetrahedron, 2012, 68, 8251-8255.
136. A. Puglisi, M. Benaglia, R. Annunziata, J. S. Siegel Immobilization of Chiral Bifunctional Organocatalysts on Poly(methylhydrosiloxane) ChemCatChem., 2012, 7, 972-974.
135. S. Guizzetti, M. Benaglia, J. S. Siegel Poly(methylhydrosiloxane)-supported chiral imidazolinones: new versatile, highly efficient and recyclable organocatalysts for stereoselective Diels-Alder cycloaddition reactions. Chem. Commun., 2012, 48, 3188-3190.

2011

134. D. Meroni, S. Ardizzone, G. Cappelletti, M. Ceotto, M. Ratti, R. Annunziata, M. Benaglia, L. Raimondi Interplay between Chemistry and Texture in Hydrophobic TiO₂ Hybrids J. Phys. Chem. C, 2011, 115, 18649.
133. S. Rossi, M. Benaglia, M. Ortenzi, E. Micotti, C. Perego, M.G. De Simoni Poly(ethylene-glycol)-based Fluorinated Esters: a Readily Available Entry for Novel ¹⁹F-MRI agents Tetrahedron Lett., 2011, 52,6581-6583.
132. A. Genoni, M. Benaglia, A. Puglisi, S. Rossi Chiral Bis-pyridinium Salts as Novel Stereoselective Catalysts for the Metal-free Diels-Alder Cycloaddition of a,b-Unsaturated Aldehydes. Synthesis, 2011, 1926-1929.
131. M. Bonsignore, M. Benaglia, R. Annunziata, G. Celentano New, readily available organocatalysts for the enantioselective reduction of a-imino- and b-imino esters Synlett, 2011, 1085-1088.
130. M. Benaglia, S. Guizzetti, S. Rossi Silicate-mediated stereoselective reactions catalyzed by chiral Lewis bases Catalytic Methods in Asymmetric Synthesis: Advanced Materials, Techniques and Applications 2011, ed. M. Gruttadauria, F. Giacalone, John Wiley and Sons.
129. S. Rossi, M. Benaglia, A. Genoni, F. Cozzi, T. Benincori Organocatalytic stereoselective direct aldol reaction of trifluoroethyl thioesters Adv. Synth. Catal., 2011, 353, 848-854.
128. A. Puglisi, L. Raimondi, M. Benaglia, L. Lay, L. Poletti Novel carbohydrate-based bifunctional organocatalysts for nucleophilic addition to nitroolefins and imines Org. Biomol. Chem., 2011, 9, 3295-3302.
127. S. Rossi, M. Benaglia, A. Genoni, T. Benincori, G. Celentano Biheteroaromatic diphosphine oxides-catalyzed stereoselective direct aldol reactions Tetrahedron, 2011, 67,158-166.
126. S. Guizzetti, M. Benaglia, M. Bonsignore, L. Raimondi Triclorosilane-mediated stereoselective synthesis of b-amino esters and their conversion to highly enantiomerically enriched b-lactams. Org. Biomol. Chem., 2011, 9, 739-743.

1991 - 2010 - 1991

125. M. Benaglia, F. Cozzi, A. Mazzanti, M. Mancinelli The Intramolecular Interaction of Thiophene and Furan with Aromatic and Fluoroaromatic Systems in some[3,3]meta(heterocyclo)paracyclophanes: a Combined Computational and NMR study. Chem. Eur. J., 2010, 16, 7456-7468.
124. S. Guizzetti, M. Benaglia, Trichlorosilane-mediated stereoselective reduction of carbon-nitrogen double bonds. Eur. J. Org. Chem., 2010, 5529-5541.
123. S. Rossi, M. Benaglia, Chiral Phosphine Oxides in Present-Day Organocatalysis Org. Biomol. Chem., 2010, 8,3824-3830.
122. S. Guizzetti, C. Biaggi, M. Benaglia, G. Celentano A convenient, highly stereoselective, metal-free synthesis of chiral amines Synlett, 2010, 134-136.
121. R. Annunziata, M. Benaglia, F. Cozzi, A. Mazzanti, L. Lunazzi The Intramolecular Edge-to-Face Interactions of an Aryl C-H Bond and of a Pyridine Nitrogen Lone Pair with Aromatic and Fluoroaromatic Systems in Some [3,3]Metaparacyclophanes: A Combined Computational and NMR Study. Chem. Eur. J., 2009, 15, 4373-4381.
120. S. Guizzetti, M. Benaglia Chiral organic catalysts for the enantioselective reduction of N-alkyl and N-benzyl- substituted alicyclic and cyclic imines European Patent Appl. n.EP07023240.0, September 22, 2008.
119. S. Guizzetti, M. Benaglia Process for the stereoselective reduction of ketoimines catalysed by trichlorosilane PCT/EP/2008/010079, Nov. 27, 2008. WO2009068284 (A2) — 2009-06-04
118. M. Benaglia Recoverable organic catalysts. Recoverable and Recyclable Catalysts 2009, ed. M. Benaglia, John Wiley and Sons.
117. G. Dell’Anna, M. Benaglia, R. Annunziata, F. Cozzi, G. Celentano, O. Francesconi, S. Roelens Aromatic tripodal receptors for (C₆₀-I_H)[5,6] fullerene Org. Biomol. Chem., 2009, 7,3871-3877.
116. S. Guizzetti, A. Puglisi, L. Raimondi, M. Benaglia Isophthalic acid-derived dicarbothioamides as novel metal-free catalysts in hydrogen bond-promoted reactions Synthetic Comm., 2009, 39, 3731-3742.
115. S. Guizzetti, M. Benaglia, R. Annunziata, F. Cozzi Chiral Lewis base promoted trichlorosilane reduction of ketimines. An enantioselective organocatalytic synthesis of chiral amines. Tetrahedron, 2009, 65,6354-6363.
114. A. Puglisi, L. Raimondi, M. Benaglia, M. Bonsignore, S. Rossi Enantioselective catalytic addition of nitroesters to N-carboalkyloxy imines: a route to quaternary stereocenters. Tetrahedron Lett., 2009, 50,4340-4342.
113. S. Guizzetti, M. Benaglia, S. Rossi Highly stereoselective metal-free catalytic reduction of imines: an easy entry to enantiomerically pure amines and natural and unnatural α-amino esters. Org. Lett., 2009, 11, 2928-2931.
112. S. Guizzetti, M. Benaglia, G. Celentano 1,1’-binaphthyldiamine-based Lewis bases as readily available and efficient organocatalysts for the reduction of N-aryl and N-alkyl ketimines Eur. J. Org. Chem., 2009,3683-3687.
111. C. Biaggi, M. Benaglia, R. Annunziata, S. Rossi, Stereoselective synthesis and characterization of new enantiomerically pure phosphoric acids Chirality, 2010, 22, 369-378.
110. G. Dell’Anna, M. Benaglia, R. Annunziata, F. Cozzi, O. Francesconi, S. Roelens Aromatic tripodal receptors for (C-60-I-h)[5,6]fullerene Org. Biomol. Chem, 2009, 7, 3871-3877.
109. R. Annunziata, M. Benaglia, F. Cozzi, A. Mazzanti, L. Lunazzi The Intramolecular Edge-to-Face Interactions of an Aryl C-H Bond and of a Pyridine Nitrogen Lone Pair with Aromatic and Fluoroaromatic Systems in Some [3,3]Metaparacyclophanes: A Combined Computational and NMR Study. Chem. Eur. J., 2009, 15, 4373-4381.
108. A. Puglisi, R. Annunziata, M. Benaglia, F. Cozzi, A. Gervasini, V. Bertacche, M. C. Sala Hybrid inorganic-organic materials carrying tertiary amine and thiourea residues tethered on mesoporous silica nanoparticles: synthesis, characterization and cooperative catalysis. Adv. Synth. Catal., 2009, 351, 219-229.
107. S. Guizzetti, M. Benaglia, F. Cozzi, S. Rossi, G. Celentano Enantioselective catalytic reduction of ketoimines with trichlorosilane promoted by readily available chiral Lewis bases. Chirality, 2009, 21, 233-238.
106. A. Puglisi , M. Benaglia, R. Annunziata, D. Rossi Stereoselective nucleophilic addition to imines catalyzed by chiral bifunctional thiourea organocatalysts Tetrahedron Asymm., 2008, 19,2258-2264.
105. M. Benaglia Heterogenized organocatalysts for asymmetric transformations. Handbook of Asymmetric Heterogeneous Catalysis 2008, eds. K. Ding, Y. Uozomi, Wiley.VCH Verlag, Weinheim.
104. R. Annunziata, M. Benaglia, A. Puglisi, F. Cozzi, L. Raimondi Synthesis of some terpyridines disubstituted in positions 6 and 6’’ with head to tail oriented amino Eur. J. Org. Chem, 2008 ,3976-3983.
103. G. Chelucci, S. Baldino, G.A. Pinna, M. Benaglia, S. Guizzetti, L. Buffa Chiral pyridine N-Oxides derived from monoterpenes as organocatalysts for stereoselective reactions with allyltrichlorosilane and tetrachlorosilane Tetrahedron, 2008 , 64, 7574-7582.
102. V. Simonini, M. Benaglia, S. Guizzetti, L. Pignataro, G. Celentano A new class of chiral Lewis basic metal-free catalysts for stereoselective allylations of aldehydes Synlett, 2008 ,1061-1065.
101. V. Simonini, M. Benaglia, T. Benincori Novel chiral biheteroaromatic diphosphine oxides for Lewis base activation of Lewis acids in enantioselective allylation and epoxide opening Adv. Synth. Catal., 2008, 350, 561-564.
100. F. Cozzi, R. Annunziata, M. Benaglia, K. Baldridge, G. Aguirre, J. Estrada, Y. Sritana-Anant. J.S. Siegel Through-space interactions between parallel-offset arenes at the van der Waals distance: 1,8-diarylbiphennylene syntheses, structure and QM computations Phys. Chem. Chem Phys., 2008 , 10, 2686-2694.
99. M. Benaglia, S. Guizzetti, L. Pignataro, Steroselective reactions involving hypervalent silicate complexes Coord. Chem. Rev., 2008 , 252, 492-512.
98. M. Benaglia Recoverable, soluble polymer-supported organic catalysts. Ernest Schering Foundation Symposium Proceedings – Sprinter Verlag Berlin Heidelberg 2008.
97. C. Biaggi, M. Benaglia, A. Puglisi Catalysis in water: synthesis of b-amino amides by Sc (III) promoted condensation of silylketene pyridylthioacetal and imines J. Organomet. Chem, 2007, 692, 5795
96. C. Biaggi, M. Benaglia, S. Rossi, S. Proto, R. Annunziata Synthesis of new chiral cyclic 1,2-diamines and their evaluation as catalysts for enantioselective Diels-Alder reactions Tetrahedron Lett., 2007, 48, 8521-8524.
95. G. Dell’Anna, M. Benaglia, L. Raimondi, F. Cozzi An experimental reinvestigation of the role of aromatic-aromatic interactions in a templated synthesis of a macrocyclic pseudopeptide. Org. Biomol. Chem, 2007, 5, 2205-2206.
94. M. Bandini, M. Benaglia, R. Sinfisi, S. Tommasi, A. Umani-Ronchi Recoverable PEG-supported copper catalyst for highly stereocontrolled nitroaldol condensation. Org. Lett., 2007, 9, 2151-2153.
93. G. Chelucci, N. Belmonte, M. Benaglia, L. Pignataro Enantioselective allylation of aldehydes with allyltrichlorosilane promoted by new chiral dipyridylmethane N-oxides. Tetrahedron Lett., 2007, 48, 4037-4041.
92. F. Colombo, R. Annunziata, M. Benaglia Catalytic, Enantioselective allylation of a-iminoesters promoted by Silver (I) Complexes of Chiral Imines. Tetrahedron Lett., 2007, 48, 2687-2690.
91. S. Guizzetti, M. Benaglia, L. Raimondi, G. Celentano Enantioselective direct aldol reaction “on water” promoted by chiral organic catalyst. Org. Lett., 2007, 9, 1247-1250.
90. S. Orlandi, M. Benaglia, G. Dell’Anna, G. Celentano Synthesis of new C₁-symmetric bis(oxazoline) ligands with a chelating sidearm for stereoselective Mukaiyama aldol condensations. J. Organomet. Chem, 2007, 692, 2120-2124.
89. M. Benaglia, F. Cozzi, A. Puglisi Solvent-free, one pot synthesis of b-lactams by the Sc(OTf)₃-catalyzed reaction of silyl ketene thioacetals with imines Eur. J. Org. Chem., 2007,2865-2869.
88. S. Guizzetti, M. Benaglia, L. Pignataro, A. Puglisi A multifunctional proline-based organic catalyst for the enantioselective aldol reactions Tetrahedron, Asymm., 2006 , 17, 2754-2760.
87. C. Biaggi, M. Benaglia, F. Cozzi, L. Raimondi The Organocatalytic Synthesis of Dipyrromethanes by the Addition of N-Methylpyrrole to Aldehydes Tetrahedron, 2006 , 62, 12375-12379.
86. M. Benaglia, Recoverable and Recyclable Chiral Organic Catalysts New J. Chem. 2006, 30, 1525-1533.
85. F. Colombo, M. Benaglia, S. Orlandi, F. Usuelli Asymmetric Multicomponent Copper Catalyzed Synthesis of Chiral Propargylamines. J. Mol. Catal., A: Chemicals., 2006, 260, 128-134.
84. M. Bandini, M. Benaglia, T. Quinto, S. Tommasi, A. Umani-Ronchi New Recoverable Poly(ethylen glycol)-supported C₁-Diamino-oligothiophene Ligands for Pd-Promoted AAA Reactions. Adv. Synth. Catal., 2006,348, 1521-1527.
83. S. Bacchi, M. Benaglia, F. Cozzi, F. Demartin, G. Filippini, A. Gavezzotti X-ray diffraction and theoretical studies for the quantitative assessment of intermolecular arene-perfluoroaren e stacking interactions Chem., Eur. J.., 2006, 12, 3538-3546.
82. F. Colombo, R. Annunziata, L. Raimondi, M. Benaglia, Synthesis of new enantiomerically pure macrocycles containing phenanthroline subunits Chirality, 2006, 18, 446-456.
81. F. Colombo, M. Benaglia, S. Orlandi, F. Usuelli, G. Celentano A Very Mild, Enantioselective Synthesis of Propargyl-amines Catalyzed by Copper (I)-Bisimines Complexes. J. Org. Chem., 2006, 71, 2064-2070.
80. L. Pignataro, M. Benaglia, R. Annunziata, F. Cozzi, M. Cinquini Structurally simple pyridine N-oxides as efficient organocatalysts for the enantioselective allylation of aromatic aldehydes. J. Org. Chem., 2006, 71, 1458-1463.
79. M. Benaglia, A. Puglisi, O. Holczknecht, S. Quici, G. Pozzi Aerobic oxidation of alcohols to carbonyl compounds mediated by poly(ethylene glycol)-supported TEMPO radicals. Tetrahedron, 2005 , 61, 12058-12064.
78. M. Benaglia, S. Guizzetti, C. Rigamonti, A. Puglisi PEG-supported Pyridyltioesters for Racemization-free Amide Synthesis: a Reagent That Allows Simultaneous Product Formation and Removal from the Polymer. Tetrahedron, 2005, 61, 12100-12106.
77. M. Benaglia, T. Benincori, P. Mussini, T. Pilati, S. Rizzo, F. Sannicolo’ Steric and Electronic Tuning of Chiral Bis(oxazoline) Ligands with 3,3’-Bithiophene Backbone. J. Org. Chem., 2005, 70, 7488-7495.
76. S.Orlandi, R. Annunziata, M. Benaglia, F. Cozzi, L. Manzoni Synthesis of Some Oligopyridine-galactose Conjugates and their Metal Complexes: a Simple Entry to Multivalent Sugar Ligands. Tetrahedron, 2005, 61, 10048-10060.
75. S. Orlandi, F. Colombo, M. Benaglia. Chiral Diamine-Copper(I) Complexes as Asymmetric Catalysts in the Enantioselective Addition of Phenylacetylene to Imines. Synthesis, 2005, 1689-1692.
74. Luca Pignataro,Maurizio Benaglia, Mauro Cinquini, Franco Cozzi and Giuseppe Celentano. Readily Available Pyridine- and Quinoline-N-Oxides as New Organocatalysts for the Enantioselective Allylation of Aromatic Aldehydes with Allyl(trichloro)silane Chirality, 2005, 17, 396-403.
73. M. Benaglia, M. Cinquini, F. Cozzi, G. Celentano Enantioselective catalysis in water: Mukaiyama-aldol condensation promoted by copper complexes of bisoxazolines supported on poly(ethylene glycol) Org. Biomol. Chem., 2004, 2, 3401-3407.
72. M. Benaglia, D. Negri, G. Dell’Anna Enantioselective addition of phenyl and alkyl acetylenes to imines catalyzed by chiral Cu(I) complexes Tetrahedron Lett., 2004, 45, 8705-8708.
71. B. Simonelli, S. Orlandi, M. Benaglia, G. Pozzi New Perfluoroalkyl Substituted Bisoxazolines as Chiral Ligands in Asymmetric Cu(II)-Catalyzed Reactions. Eur. J. Org. Chem., 2004, 2669-2673.
70. G. Pozzi, M. Cavazzini, S. Quici, M. Benaglia, G. Dell’Anna Poly(ethylene glycol)-Supported TEMPO: an Efficient, Recoverable, Metal-free Catalyst for the Selective Oxidation of Alcohols. Org. Lett., 2004, 6, 441-443.
69. R. Annunziata, M. Benaglia, M. Cinquini, F. Cozzi, L. Raimondi A molecular gate: control of the free intramolecular rotation by application of an external signal. J.Phys. Org. Chem., 2004, 17, 749-751.
68. S. Orlandi, M. Benaglia, F. Cozzi Cu(II)-Catalyzed enantioselective aldol condensation between malonic acid hemithioesters and aldehydes Tetrahedron Lett., 2004, 45, 1747-1749.
67. A. Puglisi , M. Benaglia, M. Cinquini, F. Cozzi, G. Celentano Enantioselective 1,3-Dipolar Cycloadditions of Unsaturated Aldehydes Promoted by a Poly(ethylene glycol)-Supported Organic Catalyst. Eur. J. Org. Chem., 2004, 567-573.
66. S. Orlandi, M. Benaglia, M. Caporale, R. Annunziata Synthesis of New Enantiomerically pure C₁ and C₂-symmetric N-Alkyl-Benzimidazolium and Thiazolium Salts. Tetrahedron: Asymmetry 2003, 14, 3827-3830.
65. M. Benaglia, F. Cozzi, A. Puglisi, Polymer Supported Organic Catalysts. Chem.Rev., 2003, 103, 9, 3401-3429.
64. A. Puglisi, M. Benaglia, G. Roncan Palladium Catalyzed Synthesis of Nonsymmetrically Functionalized Bipyridines, Poly(bipyridines) and Terpyridines. Eur. J. Org. Chem., 2003, 1552-1558.
63. A. Puglisi, M. Benaglia, R. Annunziata, A. Bologna Enantiomerically Pure Phenanthroline or Bipyridine containing macrocycles: a New Class of Ligands for Asymmetric Catalysis. Tetrahedron Lett.., 2003, 44, 2947-2951.
62. R. Annunziata, M. Benaglia, M. Cinquini, F. Cozzi, A. Puglisi Sequential Stereoselective Catalysis: Two single-Flask Reactions of a Substrate in the Presence of a Bifunctional Chiral Ligand and Different Transition Metals. Eur. J. Org. Chem., 2003, 1428-1432.
61. R. Annunziata, M. Benaglia, M. Cinquini, F. Cozzi, G. Pozzi Synthesis of Perfluoroalkyl-Substituted Bis(oxazolines) as Ligands for Catalytic Enantioselective Reactions Eur. J. Org. Chem., 2003, 1191-1197.
60. R. Annunziata, M. Benaglia, M. Cinquini, F. Cozzi, F. Maggioni, A. Puglisi Efficient Synthesis of an Enantiopure b-Lactam as an Advanced Precursor of Thrombin and Tryptase Inhibitors. J. Org. Chem., 2003, 68, 2952-2955.
59. M. Benaglia, T. Danelli, G. Pozzi Synthesis of a Poly(ethylene glycol)-supported Manganese Porphyrins: Efficient, Recoverable and Recyclable Catalyst for Epoxidation of Alkenes. Org. Biomol. Chem., 2003, 1, 454-456.
58. M. Benaglia, M. Cinquini, F. Cozzi, A. Puglisi, G. Celentano Poly(ethylene-glycol)-Supported Proline: a Recyclable Aminocatalyst for the Enantioselective Synthesis of g-Nitroketones by Conjugate Addition J. Mol. Catal., A Chemicals 2003, 204-205, 157-163.
57. T. Danelli, R. Annunziata, M. Benaglia, M. Cinquini, F. Cozzi, G. Tocco Immobilization of Catalysts Derived from Cinchona Alkaloids on Modified Poly(ethylene glycol). Tetrahedron: Asymmetry 2003, 14, 461-467.
56. F. Cozzi, R. Annunziata, M. Benaglia, M. Cinquini, L. Raimondi, K.K. Baldridge, J.S. Siegel Through-space Interactions between Face-to-face, Center-to-edge Oriented Arenes: Importance of Polar-p Effects. Org. Biomol. Chem., 2003, 1, 157-162.
55. M. Benaglia, M. Caporale, A. Puglisi An Improved Methodology for the Synthesis of Enantiomerically Pure(S)-2,3-O-Cyclohexylideneglyceraldehyde. Enantiomer 2002, 7, 383-388.
54. M. Benaglia, M. Cinquini, F. Cozzi, A. Puglisi, G. Celentano Poly(ethylene glycol)-Supported Proline: a Versatile Catalyst for the Enantioselective Aldol and Iminoaldol Reactions. Adv. Synth. Catal., 2002, 344, 533-542.
53. R. Annunziata, M. Benaglia, M. Caporale, L. Raimondi Synthesis of Enantiomerically Pure C₂ Symmetric Acyclic and Cyclic 1,2-Diamines via Pinacol Coupling of Imines. Tetrahedron: Asymmetry 2002, 13, 2727-2734.
52. D. Albanese, M. Benaglia, D. Landini, A. Maia, V. Lupi, M. Penso Use of a Quaternary Ammonium Salt on a Liposoluble Poly(ethylene glycol) Matrix for Laboratory and Industrial Synthetic Applications of Phase-Transfer Catalysis. Ind. Eng. Chem. Res.., 2002, 41, 4928-2935.
51. M. Benaglia Critical Survey Covering the Year 2001: Solid Supported Synthesis Seminars in Organic Synthesis - XXVII Summer School "A. Corbella", 2002, 281-304.
50. M. Benaglia, T. Danelli, F. Fabris, D. Sperandio and G. Pozzi Poly(ethylene glycol)-Supported Tetrahydroxyphenyl Porphyrin: a Convenient, Recyclable Catalyst for Photooxidation Reactions Org. Lett., 2002, 4, 4229-4232.
49. R. Annunziata, M. Benaglia, A. Bologna ¹H and ¹³C NMR Assignments of New Oligo-bipyridine-phenanthroline Hybrids as Potential Precursors of Helicate Complexes. Magn. Reson. Chem., 2002, 40, 461-466.
48. M. Benaglia, M. Cinquini, F. Cozzi, G. Tocco Synthesis of a Poly(ethylene glycol)-tetrakis Ammonium Salt: a Recyclable Phase-transfer Catalyst of Improved Catalytic Efficiency. Tetrahedron Lett.., 2002, 43, 3391-3393.
47. M. Benaglia, G. Celentano, M. Cinquini, F. Cozzi, A. Puglisi Poly(ethylene glycol)-Supported Chiral Imidazolidin-4-one: an Efficient Organic Catalyst for the Enantioselective Diels-Alder Cycloaddition. Adv. Synth. Catal., 2002, 344, 149-152.
46. R. Annunziata, M. Benaglia, M. Cinquini, F. Cozzi, A. Puglisi Efficient and Highly Stereoselective Synthesis of a b-Lactam Inhibitor of the Serine Protease Prostate-Specific Antigen. Bioorg. Med. Chem., 2002, 10, 1813-1818.
45. R. Annunziata, M. Benaglia, M. Cinquini, F. Cozzi Poly(ethylene glycol)-Supported 4-Alkylthio-Substituted Aniline – A Useful Starting Material for the Soluble Polymer-Supported Synthesis of Imines and 1,2,3,4-Tetrahydroquinolines. Eur. J. Org. Chem., 2002, 1184-1190.
44. R. Annunziata, M. Benaglia, L. Raimondi Mild Synthesis of Enantiomerically Pure Imidazo-[1,2-a]azepines Mediated by Yb(Tf)₃. Tetrahedron, 2001, 57, 10357-10363.
43. R. Annunziata, M. Benaglia, M. Cinquini, F. Cozzi, M. Pitillo Poly(ethylene glycol)-Supported Bisosaxolines as Ligands for Catalytic Enantioselective Synthesis. J. Org. Chem., 2001, 66, 3160-3166.
42. R. Annunziata, M. Benaglia, A. Famulari, L. Raimondi Structural Elucidation of Bipyridine Helicates Complexes and Their Precursors by NMR Spetroscopy. Magn. Res. Chem., 2001, 39, 341-354.
41. M. Benaglia, F. Ponzini, C. R. Woods, and J. S. Siegel Synthesis of Oligopyridines and Their Metal Complexes as Precursors to Topological Stereoisomers. Org. Lett., 2001, 3, 967-969.
40. S. Toyota, C.R. Woods, M. Benaglia, R. Haldimann, K. Warnmark, K. Hardcastle, J.S.Siegel Tetranuclear Copper(I)-Biphenanthroline Gridwork: Violation of the Principle of Maximal Donor Coordination Caused by Intercalation and CH-to-N Forces. Angew. Chem. Int. Ed. 2001, 40, 4, 751-753.
39. C.R. Woods, M. Benaglia, S. Toyota, K. Hardcastle, J.S.Siegel Trinuclear Copper(I)-Bipyridine Triskelion: Template/Bascule Control of Coordination Complex Stereochemistry in a Trefoil Knot Precursor.Angew. Chem. Int. Ed., 2001, 40, 4, 749-751.
38. M. Benaglia , L. Raimondi Stereoselection in Reactions of Chiral Allyl Ethers: The Case of 1,3-Dipolar Cycloaddition Eur. J. Org. Chem., 2001, 1033-1043.
37. M. Benaglia, G. Celentano, F. Cozzi Enantioselective Aldol Condensation Catalyzed by Poly(ethylene glicol)-Supported Proline. Adv. Synth. Catal., 2001, 343, 2, 171-173.
36. R. Annunziata, M. Benaglia, M. Cinquini, F. Cozzi Synthesis of a Bifunctional Ligand for the Sequential Enantioselective Catalysis of Various Reactions. Eur. J. Org. Chem., 2001, 1045-1048.
35. R. Annunziata, M. Benaglia, M. Cinquini, F. Cozzi, C.R. Woods, J.S. Siegel Long-Distance Propagation of Stereochemical Information by Stereoselective Synthesis of Copper(I) Bipyridine Helicates. Eur. J. Org. Chem., 2001, 173.
34. R. Annunziata, M. Benaglia, M. Cinquini, F. Cozzi, G. Tocco A Poly(ethylene glycol)-Supported Quaternary Ammonium Salt: an Efficient, Recoverable, and Recyclable Phase-Transfer Catalyst. Org. Lett. , 2000, 2, 1737.
33. M. Benaglia, M. Cinquini, F. Cozzi Stereoselective Synthesis of Enantiomerically Pure Drugs. In: New Trends in Medicinal Chemistry - Ed. F. Gualtieri, Wiley, Weinheim, pp. 97- 133, Chapter 5, 2000.
32. M. Benaglia, M. Cinquini, F. Cozzi The S-Thiolester Enolate/Imine Condensation: a Short-cut to b-Lactams. Eur. J. Org. Chem., 2000, 563.
31. R. Annunziata, M. Benaglia, M. Cinquini, F. Cozzi Soluble Polymer Supported Synthesis of b-Lactams on a Modified Poly(ethylene glycol). Chem.Eur. J., 2000, 6, 133.
30. R. Annunziata, M. Benaglia, M. Cinquini, F. Cozzi Stereoselective Synthesis of 2-Azetidinones as Cholesterol Adsorption Inhibitors. Tetrahedron: Asymmetry 1999, 10, 4841.
29. R. Annunziata, M. Benaglia, M. Cinquini, L. Raimondi The Effect of Lewis Acids on the Pinacol Homocoupling Reaction of Aldehydes Promoted by Samarium Diiodide. Eur. J. Org. Chem., 1999, 3369.
28. R. Annunziata, M. Benaglia, M. Cinquini, F. Cozzi, L. Poletti, L. Raimondi and A. Perboni A Novel Approach to the Synthesis of Precursors of Tricyclic b-Lactams Antibiotics. Eur. J. Org. Chem., 1999, 3067.
27. M. Benaglia, M. Cinquini, F. Cozzi Improved Procedure for the Purification of PEG Bound Molecules by the Use of Trioctylamine. Tetrahedron Lett., 1999, 40, 2019.
26. R. Annunziata, M. Benaglia, M. Cinquini, F. Cozzi, F. Montanari, L. Raimondi Stereoselective Synthesis of New b-Lactams by Cyclocondensation of 1-Methoxy-3- (trimethylsilyloxy)-1,3-Butadiene with 4-Formyl Substituted Azetidinones. Il Farmaco, 1998, 53, 629.
25. M. Benaglia, R. Annunziata, M. Cinquini, F. Cozzi, and S. Ressel Synthesis of New Poly(ethyleneglycol)s with a High Loading Capacity. J. Org. Chem., 1998, 63, 8628.
24. R. Annunziata, M. Benaglia, M. Cinquini, F. Cozzi and L. Raimondi The Importance of Electrostatic Interations in the Stereoselective 1,3-Dipolar Cycloadditions of Nitrones to Chiral Allyl Ethers: an Experimental and Force Field Approach. Eur. J. Org. Chem., 1998, 1823-1832.
23. M. Benaglia and L. Raimondi. Stereoselection in Pinacol Coupling Reactions of C=O and C=N Bonds . Seminars in Organic Synthesis - XXIII Summer School "A. Corbella", 1998, 155.
22. R. Annunziata, M. Benaglia, M. Cinquini, F. Cozzi and L. Raimondi Diastereoselective Synthesis of 1,2-Diphenyl-1,2-Diaminoethanes by Yb(OTf)3 Accelerated Reductive Coupling of Imines. Tetrahedron Lett., 1998, 39, 3333.
21. S. Toyota, C.R. Woods, M. Benaglia and J.S. Siegel. Synthesis of Unsymmetrical 2,8- and 2,9- Dihalophenanthrolines and Derivatives. Tetrahedron Lett., 1998, 39, 2697.
20. V. Molteni, R. Annunziata, M. Benaglia, F. Cozzi and M. Cinquini Soluble Polymer-Supported Synthesis of Imines and β-Lactams. Tetrahedron Lett., 1998, 39, 1257.
19. M. Benaglia, S. Toyota, C.R. Woods and J.S. Siegel. Palladium Catalyzed Stannylation of Halopyridines with Hexamethyldistannane. Tetrahedron Lett., 1997, 38, 4737.
18. R. Annunziata, M. Benaglia, M. Cinquini and L. Raimondi Diazomethane Cycloadditions to g-Alkoxy-a,b-unsaturated Esters: a Violation of the Inside Alkoxy Theory? Rzepa, M.S.; Syndner,J.; Eds. (CD-ROM) - Royal Society of Chemistry Publications, 1996. CD-ROM included in J. Chem.Soc., Chem. Commun. 1997, n° 6.
17. C.R. Woods, M. Benaglia, J.S. Siegel, F. Cozzi. Enantioselective Synthesis of Copper(I) Bipyridine Based Helicates by Chiral Templating of Secondary Structure: Transmission of Stereochemistry on the Nanometer Scale . Angew. Chem. Int. Ed. Engl., 1996, 35,1830.
16. R. Annunziata, M. Benaglia, M. Cinquini, F. Cozzi, O. Martini, V. Molteni. Stereoselective One-pot Synthesis of β-Lactams by Reaction of 2-Pyridylthioester with Imines in the Presence of AlBr₃ or EtAlCl₂. Tetrahedron, 1996, 52, 2583.
15. R. Annunziata, M. Benaglia, A. Chiovato, M. Cinquini, F. Cozzi. Highly Stereoselective Synthesis of β-Lactams by Condensation of the Titanium Enolate of a Chiral 2-Pyridylthioester with Chiral Imines. Tetrahedron, 1995, 51, 10025.
14. R. Annunziata, M. Benaglia, M. Cinquini, F. Cozzi, V. Molteni, L. Raimondi. Optically Active Aminoalcohol Promoted Addition of 2-Pyridylthioester Boron Enolates to Imines: Enantioselective One-pot Synthesis of b-Lactams. Tetrahedron, 1995, 51, 8941.
13. R. Annunziata, M. Benaglia, M. Cinquini, F. Cozzi, L. Raimondi. 1,3-Dipolar Cycloaddition of Diazomethane to Chiral Baylis-Hillman Adducts: a Rationale for the Observed Diastereoselectivity. J. Org. Chem., 1995, 60, 4697.
12. R. Annunziata, M. Benaglia, M. Cinquini, F. Cozzi, A. Scolaro. Stereoselective electrophilic hydroxylation at C-3 of 2-azetidinones. Gazz. Chim. Ital., 1995, 125, 65.
11. R. Annunziata, M. Benaglia, M. Cinquini, F. Cozzi. Enantioselective One-pot Synthesis of β-Lactams from Achiral 2-Pyridylthioesters and Aromatic Imines. Tetrahedron Lett., 1995, 36, 613.
10. R. Annunziata, M. Benaglia, M. Cinquini, F. Cozzi, L. Raimondi. Steroselective Synthesis of β-Lactams by Condensation of Titanium Enolates of 2-Pyridylthioesters with Imines Bearing a Chiral Auxiliary. Tetrahedron, 1994, 50, 9471.
9. R. Annunziata, M. Benaglia, M. Cinquini, F. Cozzi, L. Raimondi. Synthesis of b-Lactams by Condensation of the Tin Enolates of 2-Pyridylthioesters with Imines. A Comparison between Titanium and Tin Enolates. Tetrahedron, 1994, 50, 5821.
8. R. Annunziata, M. Benaglia, M. Cinquini, F. Cozzi, F. Ponzini, L. Raimondi. Synthesis of β-Lactams by Condensation of Titanium of 2-Pyridylthioesters with Imines. Influence of the Imine Structure on the trans/cis Stereoselectivity. Tetrahedron, 1994, 50, 2939.
7. R. Annunziata, M. Benaglia, M.Cinquini, F. Cozzi, L. Raimondi. Stereoselective Synthesis of β-Lactams by Condensation of Titanium Enolates of 2-Pyridylthioesters with Imines Bearing a Chiral Auxiliary. Tetrahedron Lett., 1993, 34, 6921.
6. R. Annunziata, M. Benaglia, M. Cinquini, F. Cozzi, F. Ponzini. Stereoselective Synthesis of Azetidin-2-ones Precursors of Biologically Active syn-3-Amino-2-hydroxybutanoic Acids. J. Org. Chem., 1993, 58, 4746.
5. R. Annunziata, M. Benaglia, M. Cinquini, L. Raimondi. Electrostatic Effects in 1,3-Dipolar Cycloaddition Reactions to Chiral Allyl Ethers: a Rationale for the Experimentally Observed Diastereoselectivities. Tetrahedron, 1993, 49, 8629.
4. R. Annunziata, M. Benaglia, M. Cinquini, F. Cozzi, F. Ponzini. Synthesis of β-Lactams of High Enantiomeric Purity by Chiral Ligand Accelerated Osmylation of Racemic 4-(2-Styryl)-azetidin-2-ones. Bioorg. Med. Chem. Lett., 1993, 3, 2397.
3. M. Benaglia, M. Cinquini, L. Raimondi. Catalytic Enantioselective Homogeneous Reactions Mediated by Transition Metal Lewis Acids. Seminars in Organic Synthesis - XVIII Summer School "A. Corbella", 1993, 155.
2. R. Annunziata, M. Benaglia, M. Cinquini, F. Cozzi, P. Giaroni. Synthesis of Optically Active 3-(1-Hydroxyalkyl)phthalides by Stereoselective Pinacol Cross Coupling J. Org. Chem., 1992, 57,782.
1. R. Annunziata, M. Cinquini, F. Cozzi, P. Giaroni, M. Benaglia. Diastereo- and Enantioselective Synthesis of 1,2-Diols by Vanadium (II) Promoted Pinacol Cross Couplin Tetrahedron, 1991, 47, 5737.

Poster and Oral communications

3rd Congresso Nazionale di Chimica Supramolecolare (Rimini, september 1997): "Enantioselective Synthesis of Double Helicates"(poster)
12th International Conference on Organic Synthesis ( ICOS-12 ) (Venezia, july 1998): "New Polyethylene Glycol Derivatives and their Use in Soluble Supported Synthesis" (oral comm)
1st International Conference on Chemistry of Antibiotics and Related Microbial Products (ICCA-1, formerly ICSA-6) (Bologna, september 1998): "Soluble Polymer Supported Synthesis of β-Lactams" (oral comm)
11th European Symposium on Organic Chemistry (ESOC-11) (Goteborg, july 1999): "Use of Trichlorotitanium Enolates of β-Hydroxy-Pyridylthioester in a Highly Stereoselective Synthesis of βLactams"(oral comm)
COST Meeting (Vienna, may 2000): "Soluble Polymer Supported Synthesis of Small Organic Molecules" (oral comm)
36th ESF/EUCHEM Conference on Stereochemistry - Burgenstock (Burgenstock, may 2001): "Stereoselective Reactions Promoted by PEG-Supported Catalysts"(poster)
9th Meeting on Stereochemistry (Praga, june 2001): "Stereoselective Reactions Promoted by Poly(ethylene glicol)-Supported Chiral Ligands and Catalysts"(invited lecture)
XXVII Convegno Nazionale della Divisione di Chimica Organica (Trieste, september 2001): "Sintesi di Piccole Molecole Organiche, Leganti e Catalizzatori Immobilizzati su Polimero Solubile". (invited lecture for Ciamician medal from Italian Chemical Society)
COST Meeting (Vienna, april 2002): "Poly(ethylene glycol)-Supported Catalysts: New Efficient Tools for Organic Synthesis" (oral comm)
XXVII Corso Estivo "A. Corbella" - Seminari di Chimica Organica (Gargnano, june 2002)
The Merck lectureship reunion (Cambridge, september 2002)
Synthesis in organic chemistry (Cambridge, july 2003): "New enantiomerically pure phenanthroline and bipyridine macrocylces" (poster)
5th Spanish Italian Symposium on Organic Chemistry (Santiago de Compostela, Spagna, september 2004): "New chiral heterocycles as ligands and organic catalysts for enantioselective reactions"(invited lecture)
40th ESF/EUCHEM Conference on Stereochemistry - Burgenstock (Burgenstock, april 2005): "Enantioselective Synthesis of Propargyl Amines Promoted by Chiral Bis-Imines Copper (I) Complexes" (flash presentation and poster)
Conference on Catalysis and Biocatalysis in Green Chemistry (Cambridge, december 2005): "Enantioselective Allylation of Aldehydes with Allyltrichlorosilane Promoted by New Chiral Organocatalysts." (oral comm)
Ciclo di lezioni (Verona, february 2006): "CATALISI SUPPORTATA"
Conferenza COFEM (Giornate di Chimica Fisica Organica e Meccanicistica (Catania, september 2006): "Bypiridine and terpyridines-based systems for the synthesis of supramolecular devices" (plenary lecture)
"Organocatalysis Symposium" held by Ernst Schering Foundation (Berlin, Germany, 2007). (Plenary lecture)
Conferences in Nichem (2008), Bayer (Frankfurt, 2008), Zambon (2007 e 2008), Roche (Basel, 2009): "Reazioni stereoselettive promosse da catalizzatori organici e organometallici" (invited lectures)
Conference at CNR Bologna (2009): Recyclable catalysts (invited lecture)
Conference at IUPAC congress (Torino, 2007): Stereoselective reactions in water
Short presentation at ICSSE International symposium on Environmental Chemistry (Stockolm, 2009) "Lewis bases promoted stereoselective reduction of ketoimines"
45th ESF/EUCHEM Conference on Stereochemistry - Burgenstock (Burgenstock, may 2010): "Stereoselective direct aldol-type reaction catalyzed by chiral biheteroaromatic diphosphine oxides" (flash presentation and poster)
EuChems 2010 - (Nurberg, Germany, 2010): "Organocatalytic direct aldol-type reaction catalyzed by chiral diphosphine oxides" (oral presentation)
COST meeting (Action ORCA, Organocatalysis) (Berlin, Germany, 2011)(oral presentation)
WISPOC (European Winter School in Physical Organic Chemistry) (Bressanone, 2011): "Recoverable and recyclable catalysts" (lecture)
Austrian-German-French-Italian-Hungarian meeting (Goslar, Germany, 2011, plenary): "Novel chiral Lewis bases in organocatalytic reactions"
Conference at Congresso Nazionale della Società Chimica Italiana (Lecce, 2011): "Water Soluble Functionalized Polymers as New 19F MRI agents " (oral presentation)
COST meeting (Action ORCA, Organocatalysis) (Marseille, France, 2012) (oral presentation)
47th ESF/EUCHEM Conference on Stereochemistry - Burgenstock (Burgenstock, may 2012): "Stereoselective reactions promoted by supported chiral organic catalysts" (poster)
ICCOS (International Congress of Catalysis in Organic Synthesis), Moscow, Russia, 2012: "Polymethylhydrosiloxane-supported chiral organic catalysts"
COST meeting (Action ORCA, Organocatalysis) (Rome, Italy, 2012) (invited lecture)
Conference at University of Bologna (2013) New chiral catalysts and novel synthetic methodologies ( invited lecture for PhD school)
COST meeting (Action ORCA, Organocatalysis) (Amsterdam, Holland, 2013) (invited lecture)
Conference at University of Piemonte Orientale (Novara, 2013) New chiral catalysts and novel synthetic methodologies ( invited lecture for PhD school)
Conference at Congresso Nazionale della Società Chimica Italiana (Sassari, 2013) -Supported chiral catalysts in flow chemistry - (oral presentation)
Invited lecture at University of Evora, Portugal -Stereoselective organocatalytic reactions in batch and under continuous-flow conditions- (2014)
COST meeting (Action ORCA, Organocatalysis) (Palermo, Italy, 2014) (invited lecture) -Stereoselective catalytic synthesis of chiral trifluoromethyl aryl and alkyl amines-